Journal Article

PUBDB-2016-03738

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework

Julien, P. A. ; Užarević, K.Extern* ; Katsenis, A. D. ; Kimber, S. A. J. ; Wang, T. ; Farha, O. K. ; Zhang, Y. ; Casaban, J. ; Germann, L. S.Extern* ; Etter, M.DESY* ; Dinnebier, R.Extern* ; James, S. L. (Corresponding author) ; Halasz, I. (Corresponding author) ; Friscic, T. (Corresponding author)Extern*

2016
American Chemical Society Washington, DC

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Please use a persistent id in citations: doi:10.1021/jacs.5b13038

Abstract: Mechanochemistry provides a rapid, efficient route to metal−organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent.Insitu synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.

Note: (c) American Chemical Society. Post referee full text in progress (embargo 1 year from February 19, 2016).

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Contributing Institute(s):

1. DOOR-User (DOOR)
2. Experimentebetreuung PETRA III (FS-PE)

Research Program(s):

1. 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) (POF3-621)
2. 6G3 - PETRA III (POF3-622) (POF3-622)

Experiment(s):

1. PETRA Beamline P02.1 (PETRA III)

Appears in the scientific report 2016

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Database coverage:
; BIOSIS Previews ; Current Contents - Life Sciences ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 10 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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