TY  - JOUR
AU  - Julien, Patrick A.
AU  - Užarević, Krunoslav
AU  - Katsenis, Athanassios D.
AU  - Kimber, Simon A. J.
AU  - Wang, Timothy
AU  - Farha, Omar K.
AU  - Zhang, Yuancheng
AU  - Casaban, José
AU  - Germann, Luzia S.
AU  - Etter, Martin
AU  - Dinnebier, Robert
AU  - James, Stuart L.
AU  - Halasz, Ivan
AU  - Friscic, Tomislav
TI  - In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework
JO  - Journal of the American Chemical Society
VL  - 138
IS  - 9
SN  - 1520-5126
CY  - Washington, DC
PB  - American Chemical Society
M1  - PUBDB-2016-03738
SP  - 2929 - 2932
PY  - 2016
N1  - (c) American Chemical Society. Post referee full text in progress (embargo 1 year from February 19, 2016).
AB  - Mechanochemistry provides a rapid, efficient route to metal−organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent.Insitu synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000371945800015
C6  - pmid:26894258
DO  - DOI:10.1021/jacs.5b13038
UR  - https://bib-pubdb1.desy.de/record/308527
ER  -