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100 1 _ |a Julien, Patrick A.
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245 _ _ |a In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework
260 _ _ |a Washington, DC
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|b American Chemical Society
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500 _ _ |a (c) American Chemical Society. Post referee full text in progress (embargo 1 year from February 19, 2016).
520 _ _ |a Mechanochemistry provides a rapid, efficient route to metal−organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent.Insitu synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.
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700 1 _ |a Užarević, Krunoslav
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700 1 _ |a Katsenis, Athanassios D.
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700 1 _ |a Kimber, Simon A. J.
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700 1 _ |a Wang, Timothy
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700 1 _ |a Farha, Omar K.
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700 1 _ |a Zhang, Yuancheng
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700 1 _ |a Casaban, José
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700 1 _ |a Germann, Luzia S.
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700 1 _ |a Etter, Martin
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700 1 _ |a Dinnebier, Robert
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700 1 _ |a James, Stuart L.
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700 1 _ |a Halasz, Ivan
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700 1 _ |a Friscic, Tomislav
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773 _ _ |a 10.1021/jacs.5b13038
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