%0 Journal Article
%A Julien, Patrick A.
%A Užarević, Krunoslav
%A Katsenis, Athanassios D.
%A Kimber, Simon A. J.
%A Wang, Timothy
%A Farha, Omar K.
%A Zhang, Yuancheng
%A Casaban, José
%A Germann, Luzia S.
%A Etter, Martin
%A Dinnebier, Robert
%A James, Stuart L.
%A Halasz, Ivan
%A Friscic, Tomislav
%T In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework
%J Journal of the American Chemical Society
%V 138
%N 9
%@ 1520-5126
%C Washington, DC
%I American Chemical Society
%M PUBDB-2016-03738
%P 2929 - 2932
%D 2016
%Z (c) American Chemical Society. Post referee full text in progress (embargo 1 year from February 19, 2016).
%X Mechanochemistry provides a rapid, efficient route to metal−organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent.Insitu synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual stepwise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000371945800015
%$ pmid:26894258
%R 10.1021/jacs.5b13038
%U https://bib-pubdb1.desy.de/record/308527