guest ::
| Home > Publications database > Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics |
| Home > Publications database > Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics |
| Journal Article | PUBDB-2016-06076 |
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
2016
Dt. Physikalische Ges.
[Bad Honnef]
This record in other databases: 
Please use a persistent id in citations: doi:10.1088/1367-2630/18/10/103011 doi:10.3204/PUBDB-2016-06076
Abstract: Ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbital and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)$_5$ in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given—which will be covered experimentally by upcoming transform-limited x-ray sources.
; 
; 
; 
; Current Contents - Physical, Chemical and Earth Sciences ; DOAJ Seal ; Ebsco Academic Search ; IF < 5 ; JCR ; Nationallizenz
; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
|
The record appears in these collections: |
PDF
PDF (PDFA)