Journal Article

PUBDB-2025-02090

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png The origin of magneto-structural coupling in Fe-based bulk metallic glasses

Firlus, A. (Corresponding author)Extern* ; Stoica, M.Extern* ; Wright, J. ; Sun, X.Extern*DESY* ; Schäublin, R. E.Extern* ; Löffler, J. F. (Corresponding author)Extern*

2025
Elsevier Lausanne

This record in other databases:  

Please use a persistent id in citations: doi:10.1016/j.jallcom.2025.180013  doi:10.3204/PUBDB-2025-02090

Abstract: All ferromagnetic Fe-based bulk metallic glasses show the Invar effect. It is a magnetic effect that reduces the coefficient of thermal expansion and comes in two forms, a step-type and a peak-type effect. Here, we study the atomic arrangement of an (Fe$_{71.2}$B$_{24}$Y$_{4.8}$)$_{96}$Nb$_4$ bulk metallic glass as a function of temperature and across more than six orders of magnitude in length scale. Combining various synchrotron-based X-ray scattering techniques we show that the Invar effect originates at the atomic scale within the Fe–Fe network. We find no signs of increased spatial correlations due to the ferromagnetic interactions. This shows that no structural rearrangement occurs at the Curie temperature and that the Invar effect is purely of energetic nature. We conclude that the Invar effect has a fundamental base that results from the magnetic interactions of Fe–Fe bonds. Based on this, we provide a model for the magnetic interactions that create the Invar effect in amorphous materials.

---

Contributing Institute(s):

1. FS DOOR-User (FS DOOR-User)
2. Experimentebetreuung PETRA III (FS-PET-S)

Research Program(s):

1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
3. FS-Proposal: I-20210311 EC (I-20210311-EC) (I-20210311-EC)

Experiment(s):

1. PETRA Beamline P62 (PETRA III)

Appears in the scientific report 2025

---

Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

---