Journal Article

PUBDB-2025-01671

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Structural insights of mechanochemically amorphised MIL-125-NH$_2$

Shaw, E. V.Extern* ; Castillo-Blas, C.Extern* ; Lambden, T. ; de Santos, B. ; Turner, B. ; Lampronti, G. I. ; Laulainen, J. E. M. ; Robertson, G. P.Extern* ; Chester, A. M.Extern* ; Ye, C.Extern* ; Guan, S. ; Karlsson, J. K. G. ; Martinez, V.Extern* ; Brekalo, I.Extern* ; Karadeniz, B.Extern* ; Cabrera, S. ; McHugh, L. N. ; Užarević, K.Extern* ; Alemán, J. ; Fraile, A. ; Evans, R. C. ; Midgley, P. A. ; Keen, D. A.Extern*XFEL.EU* ; Moya, X. ; Bennett, T. D. (Corresponding author)Extern*

2025
Soc. Cambridge

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Please use a persistent id in citations: doi:10.1039/D4CC06320A  doi:10.3204/PUBDB-2025-01671

Abstract: In this work, we investigated the response of the metal–organic framework MIL-125-NH$_2$ to ball-milling. Both localised and bulk analyses revealed prolongued ball-milling results in a complete loss of long-range structural order. Investigation of this disorder revealed partial retention of the local bonding of the secondary building unit, suggesting structure collapse progressed primarily through metal–linker bond breakage. We explored the photocatalytic performance of the materials, and examined the materials’ band gap using UV-Vis reflectance spectroscopy.

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Contributing Institute(s):

1. FS DOOR-User (FS DOOR-User)

Research Program(s):

1. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
2. FS-Proposal: I-20221330 EC (I-20221330-EC) (I-20221330-EC)
3. FS-Proposal: I-20230031 (I-20230031) (I-20230031)

Experiment(s):

1. PETRA Beamline P02.1 (PETRA III)

Appears in the scientific report 2025

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Database coverage:
; ; ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; Index Chemicus ; JCR ; National-Konsortium ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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