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@ARTICLE{Shaw:627896,
author = {Shaw, Emily V. and Castillo-Blas, Celia and Lambden,
Timothy and de Santos, Beatriz and Turner, Bethan and
Lampronti, Giulio I. and Laulainen, Joonatan E. M. and
Robertson, Georgina P. and Chester, Ashleigh M. and Ye,
Chumei and Guan, Shaoliang and Karlsson, Joshua K. G. and
Martinez, Valentina and Brekalo, Ivana and Karadeniz, Bahar
and Cabrera, Silvia and McHugh, Lauren N. and Užarević,
Krunoslav and Alemán, Jose and Fraile, Alberto and Evans,
Rachel C. and Midgley, Paul A. and Keen, David A. and Moya,
Xavier and Bennett, Thomas D},
title = {{S}tructural insights of mechanochemically amorphised
{MIL}-125-{NH}$_2$},
journal = {Chemical communications},
volume = {61},
number = {26},
issn = {0022-4936},
address = {Cambridge},
publisher = {Soc.},
reportid = {PUBDB-2025-01671},
pages = {5019 - 5022},
year = {2025},
abstract = {In this work, we investigated the response of the
metal–organic framework MIL-125-NH$_2$ to ball-milling.
Both localised and bulk analyses revealed prolongued
ball-milling results in a complete loss of long-range
structural order. Investigation of this disorder revealed
partial retention of the local bonding of the secondary
building unit, suggesting structure collapse progressed
primarily through metal–linker bond breakage. We explored
the photocatalytic performance of the materials, and
examined the materials’ band gap using UV-Vis reflectance
spectroscopy.},
cin = {FS DOOR-User},
ddc = {540},
cid = {$I:(DE-H253)FS_DOOR-User-20241023$},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20221330
EC (I-20221330-EC) / FS-Proposal: I-20230031 (I-20230031)},
pid = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20221330-EC /
G:(DE-H253)I-20230031},
experiment = {EXP:(DE-H253)P-P02.1-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:40059691},
UT = {WOS:001440412100001},
doi = {10.1039/D4CC06320A},
url = {https://bib-pubdb1.desy.de/record/627896},
}