TY  - JOUR
AU  - Shaw, Emily V.
AU  - Castillo-Blas, Celia
AU  - Lambden, Timothy
AU  - de Santos, Beatriz
AU  - Turner, Bethan
AU  - Lampronti, Giulio I.
AU  - Laulainen, Joonatan E. M.
AU  - Robertson, Georgina P.
AU  - Chester, Ashleigh M.
AU  - Ye, Chumei
AU  - Guan, Shaoliang
AU  - Karlsson, Joshua K. G.
AU  - Martinez, Valentina
AU  - Brekalo, Ivana
AU  - Karadeniz, Bahar
AU  - Cabrera, Silvia
AU  - McHugh, Lauren N.
AU  - Užarević, Krunoslav
AU  - Alemán, Jose
AU  - Fraile, Alberto
AU  - Evans, Rachel C.
AU  - Midgley, Paul A.
AU  - Keen, David A.
AU  - Moya, Xavier
AU  - Bennett, Thomas D
TI  - Structural insights of mechanochemically amorphised MIL-125-NH<sub>2</sub>
JO  - Chemical communications
VL  - 61
IS  - 26
SN  - 0022-4936
CY  - Cambridge
PB  - Soc.
M1  - PUBDB-2025-01671
SP  - 5019 - 5022
PY  - 2025
AB  - In this work, we investigated the response of the metal–organic framework MIL-125-NH<sub>2</sub> to ball-milling. Both localised and bulk analyses revealed prolongued ball-milling results in a complete loss of long-range structural order. Investigation of this disorder revealed partial retention of the local bonding of the secondary building unit, suggesting structure collapse progressed primarily through metal–linker bond breakage. We explored the photocatalytic performance of the materials, and examined the materials’ band gap using UV-Vis reflectance spectroscopy. 
LB  - PUB:(DE-HGF)16
C6  - pmid:40059691
UR  - <Go to ISI:>//WOS:001440412100001
DO  - DOI:10.1039/D4CC06320A
UR  - https://bib-pubdb1.desy.de/record/627896
ER  -