Journal Article

PUBDB-2023-05464

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png In situ impregnated Ni/Al$_2$O$_3$ catalysts prepared by binder jet 3D printing using nickel nitrate-containing ink

Bui, H. M.Extern* ; Kratky, T. ; Lee, I.Extern* ; Khare, R.Extern* ; Hiller, M. ; Wedig, S. ; Günther, S. ; Hinrichsen, O. (Corresponding author)

2023
Elsevier Amsterdam

This record in other databases:    

Please use a persistent id in citations: doi:10.1016/j.catcom.2023.106738  doi:10.3204/PUBDB-2023-05464

Abstract: The binder jetting printing technique enables in situ impregnation of alumina using a Ni(NOl$_3$)l$_2$-containing ink (NI), facilitating omission of impregnation. NI was compared to wet impregnation (WI). Full characterization by quasi-in situ XPS, XAS and TPR revealed the presence of Ni as NiAll$_2$Ol$_4$ spinel. TPR analysis identified surface NiO and NiAl$_2$Ol$_4$ species with facilitated reduction by NI, in addition to the respective species in bulk form. Post-processing affects active site accessibility by coverage. 3D printing limited the Ni loading, but XPS revealed higher metal dispersion by NI. COl$_2$ hydrogenation confirmed active Ni/All$_2$Ol$_3$ catalysts with enhanced activity by NI.

---

Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)
2. Technische Universität München (TUM)

Research Program(s):

1. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)

Experiment(s):

1. PETRA Beamline P65 (PETRA III)

Appears in the scientific report 2023

---

Database coverage:
; ; ; ; Article Processing Charges ; BIOSIS Previews ; Biological Abstracts ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DOAJ Seal ; Ebsco Academic Search ; Essential Science Indicators ; Fees ; IF < 5 ; Index Chemicus ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

---