Journal Article

PUBDB-2020-00200

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Reversible coordination-induced spin-state switching in complexes on metal surfaces

Köbke, A. ; Gutzeit, F. ; Röhricht, F. ; Schlimm, A. ; Grunwald, J. ; Tuczek, F. ; Studniarek, M. ; Longo, D. ; Choueikani, F. ; Otero, E. ; Ohresser, P. ; Rohlf, S.Extern* ; Johannsen, S. ; Diekmann, F.Extern* ; Rossnagel, K.DESY* ; Weismann, A. ; Jasper-Toennies, T. ; Näther, C. ; Herges, R. (Corresponding author) ; Berndt, R. ; Gruber, M. (Corresponding author)Extern*

2020
Nature Publishing Group London [u.a.]

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Please use a persistent id in citations: doi:10.1038/s41565-019-0594-8  doi:10.3204/PUBDB-2020-00200

Abstract: Molecular spin switches are attractive candidates for controlling the spin polarization developing at the interface between molecules and magnetic metal surfaces, which is relevant for molecular spintronics devices. However, so far, intrinsic spin switches such as spin-crossover complexes have suffered from fragmentation or loss of functionality following adsorption on metal surfaces, with rare exceptions. Robust metal–organic platforms, on the other hand, rely on external axial ligands to induce spin switching. Here we integrate a spin switching functionality into robust complexes, relying on the mechanical movement of an axial ligand strapped to the porphyrin ring. Reversible interlocked switching of spin and coordination, induced by electron injection, is demonstrated on Ag(111) for this class of compounds. The stability of the two spin and coordination states of the molecules exceeds days at 4 K. The potential applications of this switching concept go beyond the spin functionality, and may turn out to be useful for controlling the catalytic activity of surfaces.

Note: © Springer Nature Limited

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Contributing Institute(s):

1. FS-SXQM (FS-SXQM)

Research Program(s):

1. 6212 - Quantum Condensed Matter: Magnetism, Superconductivity (POF3-621) (POF3-621)

Experiment(s):

1. No specific instrument

Appears in the scientific report 2020

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Database coverage:
; ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 30 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection

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