TY  - JOUR
AU  - Köbke, Alexander
AU  - Gutzeit, Florian
AU  - Röhricht, Fynn
AU  - Schlimm, Alexander
AU  - Grunwald, Jan
AU  - Tuczek, Felix
AU  - Studniarek, Michał
AU  - Longo, Danilo
AU  - Choueikani, Fadi
AU  - Otero, Edwige
AU  - Ohresser, Philippe
AU  - Rohlf, Sebastian
AU  - Johannsen, Sven
AU  - Diekmann, Florian
AU  - Rossnagel, Kai
AU  - Weismann, Alexander
AU  - Jasper-Toennies, Torben
AU  - Näther, Christian
AU  - Herges, Rainer
AU  - Berndt, Richard
AU  - Gruber, Manuel
TI  - Reversible coordination-induced spin-state switching in complexes on metal surfaces
JO  - Nature nanotechnology
VL  - 15
IS  - 1
SN  - 1748-3395
CY  - London [u.a.]
PB  - Nature Publishing Group
M1  - PUBDB-2020-00200
SP  - 18 - 21
PY  - 2020
N1  - © Springer Nature Limited
AB  - Molecular spin switches are attractive candidates for controlling the spin polarization developing at the interface between molecules and magnetic metal surfaces, which is relevant for molecular spintronics devices. However, so far, intrinsic spin switches such as spin-crossover complexes have suffered from fragmentation or loss of functionality following adsorption on metal surfaces, with rare exceptions. Robust metal–organic platforms, on the other hand, rely on external axial ligands to induce spin switching. Here we integrate a spin switching functionality into robust complexes, relying on the mechanical movement of an axial ligand strapped to the porphyrin ring. Reversible interlocked switching of spin and coordination, induced by electron injection, is demonstrated on Ag(111) for this class of compounds. The stability of the two spin and coordination states of the molecules exceeds days at 4 K. The potential applications of this switching concept go beyond the spin functionality, and may turn out to be useful for controlling the catalytic activity of surfaces.
LB  - PUB:(DE-HGF)16
C6  - pmid:31873288
UR  - <Go to ISI:>//WOS:000507726200002
DO  - DOI:10.1038/s41565-019-0594-8
UR  - https://bib-pubdb1.desy.de/record/434639
ER  -