Home > Publications database > An integrated cleanroom process for the vapor-phase deposition of large-area zeolitic imidazolate framework thin films |
Journal Article | PUBDB-2019-03805 |
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
2019
American Chemical Society
Washington, DC
This record in other databases:
Please use a persistent id in citations: doi:10.1021/acs.chemmater.9b03435 doi:10.3204/PUBDB-2019-03805
Abstract: Robust and scalable thin film deposition methods are key to realize the potential of metal-organic frameworks (MOFs) in electronic devices. Here, we report the first integration of the chemical vapor deposition (CVD) of MOF coatings in a custom reactor within a cleanroom setting. As a test case, the MOF-CVD conditions for ZIF-8 are optimized to enable smooth, pinhole-free, and uniform thin films on full 200 mm wafers under mild conditions. The single-chamber MOF-CVD process and the impact of the deposition parameters are elucidated via a combination of in situ monitoring and ex situ characterization. The resulting process guidelines will pave the way for new MOF-CVD formulations and a plethora of MOF-based devices.
![]() |
The record appears in these collections: |