Journal Article

PUBDB-2018-05476

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Influence of Iodine Doping on the Structure, Morphology, and Physical Properties of Manganese Phthalocyanine Thin Films

Madhuri, K. P.Extern* ; John, N. (Corresponding author)Extern* ; Angappane, S. ; Santra, P. K.Extern* ; Bertram, F.DESY*

2018
ACS Washington, DC

This record in other databases:    

Please use a persistent id in citations: doi:10.1021/acs.jpcc.8b08205  doi:10.3204/PUBDB-2018-05476

Abstract: Doping with halide ions is a popular method toalter the properties of metal phthalocyanines (MPcs),particularly magnetic and electrical nature of organic semiconductorsfor applications in spintronic or electronic devices.Doping can cause a structural rearrangement in MPc packing,and the physical properties may be correlated with molecularpacking. Films of a planar and magnetic MPc, manganese-(II)phthalocyanine (MnPc), are chosen for iodine dopingstudy. The optical, magnetic, and electrical properties ofpristine- and iodine-doped MnPc thin films are investigatedand can be directly associated with their molecular structure.Two-dimensional grazing incidence synchrotron X-ray diffractionreveals structural disorder in MnPc films upon iodineinfusion induced by the reorientation of ordered, edge-on molecular configuration to tilted and face-on configurations in arandom fashion. The film morphology changes accordingly, where in the uniform crystallites reorganize in a disordered manner.The ferromagnetic nature of the pristine film gets weakened because of iodine species and favors antiferromagnetic coupling.The study of electrical properties at room temperature by conducting atomic force microscopy reveals that the conductance isenhanced independently of the film thickness because of the disorder induced by iodine inclusion.

Note: © American Chemical Society

---

Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)
2. PETRA III (PETRA III)

Research Program(s):

1. 6214 - Nanoscience and Materials for Information Technology (POF3-621) (POF3-621)
2. 6G3 - PETRA III (POF3-622) (POF3-622)
3. FS-Proposal: I-20170296 (I-20170296) (I-20170296)
4. INDIA-DESY - INDIA-DESY Collaboration (2020_Join2-INDIA-DESY) (2020_Join2-INDIA-DESY)

Experiment(s):

1. PETRA Beamline P08 (PETRA III)

Appears in the scientific report 2018

---

Database coverage:
; ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection

---