Journal Article

PUBDB-2018-02329

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Probing the Thermochromic Phase Transition in $\mathrm{CuMoO_{4}}$ by EXAFS Spectroscopy

Jonane, I. ; Cintins, A. ; Kalinko, A. ; Chernikov, R.DESY* ; Kuzmin, A. (Corresponding author)

2018
Wiley-VCH Weinheim

This record in other databases:    

Please use a persistent id in citations: doi:10.1002/pssb.201800074  doi:10.3204/PUBDB-2018-02329

Abstract: Extended X-ray absorption fine structure (EXAFS) spectroscopy at the Mo K-edge is used to follow the thermochromic γ-to-α phase transition in copper molybdate (CuMoO4). The temperature dependence (10–300 K) of the radial distribution function (RDF) for the Mo–O atom pairs in the first coordination shell of molybdenum atoms is reconstructed by the regularization-like method from the experimental EXAFS spectra. The analysis of the RDFs suggests that the transition occurs gradually within the two-phase coexistence range of 225–275 K. The local environment of molybdenum atoms transforms upon the γ-to-α phase transition from strongly distorted octahedral to less distorted tetrahedral coordination.

Note: © WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

---

Contributing Institute(s):

1. DOOR-User (DOOR)
2. PETRA III Extension (FS-PEX)

Research Program(s):

1. 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) (POF3-621)
2. 6G3 - PETRA III (POF3-622) (POF3-622)
3. FS-Proposal: I-20160149 EC (I-20160149-EC) (I-20160149-EC)

Experiment(s):

1. PETRA Beamline P65 (PETRA III)

Appears in the scientific report 2018

---

Database coverage:
; ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

---