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000405823 1001_ $$00000-0002-8692-3089$$aJonane, Inga$$b0
000405823 245__ $$aProbing the Thermochromic Phase Transition in $\mathrm{CuMoO_{4}}$ by EXAFS Spectroscopy
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000405823 520__ $$aExtended X-ray absorption fine structure (EXAFS) spectroscopy at the Mo K-edge is used to follow the thermochromic γ-to-α phase transition in copper molybdate (CuMoO4). The temperature dependence (10–300 K) of the radial distribution function (RDF) for the Mo–O atom pairs in the first coordination shell of molybdenum atoms is reconstructed by the regularization-like method from the experimental EXAFS spectra. The analysis of the RDFs suggests that the transition occurs gradually within the two-phase coexistence range of 225–275 K. The local environment of molybdenum atoms transforms upon the γ-to-α phase transition from strongly distorted octahedral to less distorted tetrahedral coordination.
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000405823 7001_ $$00000-0003-4027-4914$$aCintins, Arturs$$b1
000405823 7001_ $$00000-0002-0615-4735$$aKalinko, Aleksandr$$b2
000405823 7001_ $$0P:(DE-H253)PIP1008170$$aChernikov, Roman$$b3
000405823 7001_ $$00000-0003-4641-6354$$aKuzmin, Alexei$$b4$$eCorresponding author
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