Journal Article PUBDB-2016-01994

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Time-resolved pump and probe x-ray absorption fine structure spectroscopy at beamline P11 at PETRA III

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2016
American Institute of Physics [S.l.]

Review of scientific instruments 87(5), 053116 () [10.1063/1.4948596]
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Abstract: We report about the development and implementation of a new setup for time-resolved X-ray absorption fine structure spectroscopy at beamline P11 utilizing the outstanding source properties of the low-emittance PETRA III synchrotron storage ring in Hamburg. Using a high intensitymicrometer-sized X-ray beam in combination with two positional feedback systems, measurements were performed on the transition metal complex fac-Tris[2-phenylpyridinato-C2,N]iridium(III) alsoreferred to as fac-Ir(ppy)$_3$. This compound is a representative of the phosphorescent iridium(III) complexes, which play an important role in organic light emitting diode (OLED) technology. The experiment could directly prove the anticipated photoinduced charge transfer reaction. Our results further reveal that the temporal resolution of the experiment is limited by the PETRA III X-ray bunch length of ∼ 103 ps full width at half maximum (FWHM).

Classification:

Note: (c) Published by AIP Publishing. Post referee full text in progress.

Contributing Institute(s):
  1. Experimentebetreuung PETRA III (FS-PE)
  2. European XFEL (Eur.XFEL)
  3. FS-Photon Science (FS-PS)
  4. Institute of Nanostructure and Solid State Physics (UNI/INF)
  5. Direktorium (DIR)
Research Program(s):
  1. 6215 - Soft Matter, Health and Life Sciences (POF3-621) (POF3-621)
  2. 6G3 - PETRA III (POF3-622) (POF3-622)
  3. VH-VI-403 - In-Situ Nano-Imaging of Biological and Chemical Processes (2015_IFV-VH-VI-403) (2015_IFV-VH-VI-403)
  4. CUI - Hamburger Zentrum für ultraschnelle Beobachtung (194651731) (194651731)
  5. EUCALL - European Cluster of Advanced Laser Light Sources (654220) (654220)
Experiment(s):
  1. PETRA Beamline P11 (PETRA III)

Appears in the scientific report 2016
Database coverage:
Medline ; Embargoed OpenAccess ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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The record appears in these collections:
Private Collections > >Extern > >HAS-User > >FS-UNI > UNI/INF
Private Collections > >DESY > >FS > FS-PS
Private Collections > >DESY > >FS > FS-PE
Private Collections > >DESY > >DIR > DIR
Private Collections > >XFEL.EU > Eur.XFEL
Document types > Articles > Journal Article
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 Record created 2016-05-23, last modified 2025-07-17


Published on 2016-05-17. Available in OpenAccess from 2017-05-17.:
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