Journal Article

PUBDB-2016-01678

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Development of a new in situ analysis technique applying luminescence of local coordination sensors: principle and application for monitoring metal-ligand exchange processes

Terraschke, H. (Corresponding author)>Extern* ; Ruiz Arana, L.>Extern* ; Lindenberg, P.>Extern* ; Bensch, W.>Extern*

2016
Soc. Cambridge

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Please use a persistent id in citations: doi:10.1039/C6AN00075D

Abstract: Here, we introduce the principle of the novel in situ luminescence analysis of coordination sensor (ILACS) approach for monitoring the formation of solid materials, recording information from the formed solid compounds as well as from the surrounding solutions. This technique utilizes as a main tool the sensitivity of luminescence properties of lanthanide (Ln) ions on the coordination environment, being incorporated as local sensors by the investigated material during synthesis. The luminescence spectra and their environment-dependent developments are monitored in situ from the early stages of the reaction until the final product formation under real conditions with a high time resolution. The ILACS principle is demonstrated here for monitoring the formation of [Eu(phen)$_2$(NO$_3$)$_3$] (phen = 1,10-phenanthroline) and further metal-ligand exchange processes during its conversion to [Sn(phen)Cl$_4$]. These reactions were followed, for instance, analyzing the antenna effect, shift of the $^5$D$_{0}\to ^{7}$F$_4$ Eu$^{3+}$ transition and quenching effects. In addition, these results have been validated by comparison with other in situ techniques. The results demonstrate that ILACS is a new powerful, fast, broadly available in situ characterization method, which is applicable for liquids, amorphous samples, and very small crystallites besides for large crystals.

Note: (c) The Royal Society of Chemistry

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Contributing Institute(s):

1. DOOR-User (DOOR)

Research Program(s):

1. 6G3 - PETRA III (POF3-622) (POF3-622)

Experiment(s):

1. PETRA Beamline P09 (PETRA III)

Appears in the scientific report 2016

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Database coverage:
; ; ; Allianz-Lizenz / DFG ; Current Contents - Life Sciences ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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