Journal Article PUBDB-2026-02036

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A 3-GPa ductile martensitic alloy enabled by interface complexes and dislocations

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2026
Nature Publishing Group Basingstoke

Nature materials 25(3), 395 - 404 () [10.1038/s41563-026-02479-9]
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Abstract: Ultrahigh-strength bulk alloys with martensitic structures are essential for heavy-duty applications and infrastructure. However, they often contain small-angle grain boundaries (SAGBs), which enhance ductility but weaken resistance to dislocation motion. This limitation restricts tensile strength to below 2.5 GPa, even when nanoprecipitates or hierarchical architectures are introduced. Here we overcome this limitation by developing a near-single-phase martensitic alloy with a tensile strength exceeding 3 GPa. In the model (Fe$_{49}$Co$_{40}$Mo$_{11}$)$_{99.6}$B$_{0.3}$C$_{0.1}$ (at.%) alloy, cold rolling followed by low-temperature annealing introduces a high density of dislocations and drives Mo, C and B atoms to cosegregate at the SAGBs, forming interface complexes. These complexes stabilize the SAGBs, reinforce barriers to dislocation motion and still permit dislocation transmission across boundaries. As a result, the alloy achieves a tensile yield strength of 3.05 GPa and a fracture elongation of 5.13%, setting a benchmark for ultrahigh-strength, ductile alloys. This simple, scalable process integrates seamlessly with existing manufacturing methods and opens a path to next-generation structural materials.

Classification:

Contributing Institute(s):
  1. DOOR-User (DOOR ; HAS-User)
  2. PETRA-D (FS-PETRA-D)
  3. Helmholtz-Zentrum Hereon (Hereon)
Research Program(s):
  1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
  2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
Experiment(s):
  1. PETRA Beamline P02.1 (PETRA III)

Appears in the scientific report 2026
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 Record created 2026-07-06, last modified 2026-07-10


Published on 2026-01-30. Available in OpenAccess from 2026-07-30.:
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