Journal Article PUBDB-2025-02492

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Revisiting Na$_x$CoO$_2$: A renewed magnetic phase diagram based on electrochemical reaction synthesis

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2025
APS College Park, MD

Physical review research 7(2), 023138 () [10.1103/PhysRevResearch.7.023138]
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Abstract: The assertion of intrinsic material properties based on measured experimental data is being challenged by emerging sample synthesis protocols, which opens new avenues for discovering novel functionalities. In this study, we revisit one of the most widely studied strongly correlated materials of the early 2000s, Na$_𝑥$⁢CoO$_2$ (NCO). Leveraging the sensitivity of muon spin rotation and relaxation (𝜇$^+$⁢SR) measurements, we discern significant differences between NCO samples synthesized via conventional solid-state reaction (SSR) and our electrochemical reaction (ECR) approach. Contrary to SSR-synthesized Na$_{0.7}$⁢CoO$_2$, which exhibits a nonmagnetic ground state, our ECR-derived sample showcases an antiferromagnetic (AF) order from 𝑥≥0.7, challenging established phase boundaries. We attribute the observed magnetic phenomena in ECR-NCO to long-range order of Na-ions and/or vacancies, as well as the inherent flexibility of the crystal framework. Our study holds implications for tailoring and optimization of next-generation devices based on layered materials.

Classification:

Contributing Institute(s):
  1. DOOR-User (DOOR ; HAS-User)
  2. Sustainable Materials (FS-SMA)
Research Program(s):
  1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
  2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
  3. SWEDEN-DESY - SWEDEN-DESY Collaboration (2020_Join2-SWEDEN-DESY) (2020_Join2-SWEDEN-DESY)
Experiment(s):
  1. PETRA Beamline P03 (PETRA III)

Appears in the scientific report 2025
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Medline ; Creative Commons Attribution CC BY 4.0 ; DOAJ ; OpenAccess ; Article Processing Charges ; Clarivate Analytics Master Journal List ; DOAJ Seal ; Emerging Sources Citation Index ; Fees ; SCOPUS ; Web of Science Core Collection
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 Record created 2025-07-24, last modified 2025-08-10


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