% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Forslund:634408,
author = {Forslund, Ola Kenji and Sugiyama, Jun and Andreica, Daniel
and Umegaki, Izumi and Nocerino, Elisabetta and Brett,
Calvin and Roth, Stephan and Söderberg, L. Daniel and
Matsubara, Nami and Hansen, Thomas C. and Hoshikawa, Akinori
and Guerin, Elodie and Delmas, Claude and Sassa, Yasmine and
Månsson, Martin},
title = {{R}evisiting {N}a$_x${C}o{O}$_2$: {A} renewed magnetic
phase diagram based on electrochemical reaction synthesis},
journal = {Physical review research},
volume = {7},
number = {2},
issn = {2643-1564},
address = {College Park, MD},
publisher = {APS},
reportid = {PUBDB-2025-02492},
pages = {023138},
year = {2025},
abstract = {The assertion of intrinsic material properties based on
measured experimental data is being challenged by emerging
sample synthesis protocols, which opens new avenues for
discovering novel functionalities. In this study, we revisit
one of the most widely studied strongly correlated materials
of the early 2000s, Na$_𝑥$CoO$_2$ (NCO). Leveraging
the sensitivity of muon spin rotation and relaxation
(𝜇$^+$SR) measurements, we discern significant
differences between NCO samples synthesized via conventional
solid-state reaction (SSR) and our electrochemical reaction
(ECR) approach. Contrary to SSR-synthesized
Na$_{0.7}$CoO$_2$, which exhibits a nonmagnetic ground
state, our ECR-derived sample showcases an antiferromagnetic
(AF) order from 𝑥≥0.7, challenging established phase
boundaries. We attribute the observed magnetic phenomena in
ECR-NCO to long-range order of Na-ions and/or vacancies, as
well as the inherent flexibility of the crystal framework.
Our study holds implications for tailoring and optimization
of next-generation devices based on layered materials.},
cin = {DOOR ; HAS-User / FS-SMA},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-SMA-20220811},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
SWEDEN-DESY - SWEDEN-DESY Collaboration
$(2020_Join2-SWEDEN-DESY)$},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
$G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
experiment = {EXP:(DE-H253)P-P03-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1103/PhysRevResearch.7.023138},
url = {https://bib-pubdb1.desy.de/record/634408},
}