Journal Article

PUBDB-2024-05117

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Ligand Conformation Controls Assembly of a Helicate/Mesocate, Heteroleptic [Pd2L2L’2] Cages and a Six‐Jagged [Pd6L12] Ring

Benchimol, E.Extern* ; Ebbert, K. E. ; Walther, A.Extern* ; Holstein, J.Extern* ; Clever, G. (Corresponding author)Extern*

2024
Wiley-VCH Weinheim

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Please use a persistent id in citations: doi:10.1002/chem.202401850  doi:10.3204/PUBDB-2024-05117

Abstract: Molecular building blocks, capable of adopting severalstrongly deviating conformations, are of particular interest in thedevelopment of stimuli-responsive self-assemblies. The pronouncedstructural flexibility of a short acridone-based bridging ligand,equipped with two monodentate isoquinoline donors, is hereinexploited to assemble a surprisingly diverse series of coordinationdrivenPd(II) architectures. First, it can form a highly twisted Pd2L4helicate, transformable into the corresponding mesocate, controlledby temperature, counter anion and choice of solvent. Second, it alsoallows the formation of heteroleptic cages, either from a mix of ligandswith Pd(II) cations or by cage-to-cage transformation from homolepticassemblies. Here, the acridone-based ligand tolerates counterligands that carry their donors either in a diverging or convergingarrangement, as it can rotate its own coordination sites by 90° andstructurally adapt to both situations via shape complementarity. Third,by a near 180° rotation of only one of its arms, the ligand can adoptan S-shape conformation and form an unprecedented C6h-symmetricPd6L12 saw-toothed six-membered ring.

Note: open access, online pre-print, pages and volume not yet assigned

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Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)

Research Program(s):

1. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
2. FS-Proposal: I-20210921 (I-20210921) (I-20210921)
3. GRK 2376 - GRK 2376: Umgrenzungsgesteuerte Chemie (331085229) (331085229)
4. DFG project G:(GEPRIS)390677874 - EXC 2033: RESOLV (Ruhr Explores Solvation) (390677874) (390677874)

Experiment(s):

1. PETRA Beamline P11 (PETRA III)

Appears in the scientific report 2024

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Database coverage:
; ; ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; Index Chemicus ; JCR ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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