Journal Article

PUBDB-2023-04454

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Increasing complexity in adamantyl thioethers characterized by rotational spectroscopy

Pinacho Morante, P. (Corresponding author)Extern*DESY* ; Loru, D.Extern*DESY* ; Šumanovac, T. ; Šekutor, M. (Corresponding author) ; Schnell, M. (Corresponding author)CFEL*DESY*

2023
Wiley-VCH Verl. Weinheim

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Please use a persistent id in citations: doi:10.1002/cphc.202300561  doi:10.3204/PUBDB-2023-04454

Abstract: We report on the synthesis and characterization using high-resolution rotational spectroscopy of three bulky thioethers that feature an adamantyl group connected to a sulfur atom. Detailed experimental and theoretical structures are provided and compared with the 1,1'-diadamantyl ether. In addition, we expand on previous findings concerning microsolvation of adamantyl derivatives by investigating the cluster formation between these thioethers and a water molecule. The investigation of such clusters provides valuable insights into the sulfur-centered hydrogen bonding in thioethers with increasing size and steric repulsion.

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Contributing Institute(s):

1. Spectroscopy of molecular processes (FS-SMP)
2. FS-Photon Science (FS-PS)
3. DOOR-User (DOOR ; HAS-User)
4. FS Photon Science (PhotonScience)

Research Program(s):

1. 631 - Matter – Dynamics, Mechanisms and Control (POF4-631) (POF4-631)

Experiment(s):

1. No specific instrument

Appears in the scientific report 2023

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Database coverage:
; ; ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Essential Science Indicators ; IF < 5 ; Index Chemicus ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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