TY  - JOUR
AU  - Pinacho Morante, Pablo
AU  - Loru, Donatella
AU  - Šumanovac, Tatjana
AU  - Šekutor, Marina
AU  - Schnell, Melanie
TI  - Increasing complexity in adamantyl thioethers characterized by rotational spectroscopy
JO  - ChemPhysChem
VL  - 24
IS  - 23
SN  - 1439-4235
CY  - Weinheim
PB  - Wiley-VCH Verl.
M1  - PUBDB-2023-04454
SP  - e202300561
PY  - 2023
AB  - We report on the synthesis and characterization using high-resolution rotational spectroscopy of three bulky thioethers that feature an adamantyl group connected to a sulfur atom. Detailed experimental and theoretical structures are provided and compared with the 1,1'-diadamantyl ether. In addition, we expand on previous findings concerning microsolvation of adamantyl derivatives by investigating the cluster formation between these thioethers and a water molecule. The investigation of such clusters provides valuable insights into the sulfur-centered hydrogen bonding in thioethers with increasing size and steric repulsion.
LB  - PUB:(DE-HGF)16
C6  - 37673788
UR  - <Go to ISI:>//WOS:001077614000001
DO  - DOI:10.1002/cphc.202300561
UR  - https://bib-pubdb1.desy.de/record/587715
ER  -