Journal Article

PUBDB-2022-03141

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png In Situ Surface-Sensitive Investigation of Multiple Carbon Phases on Fe(110) in the Fischer–Tropsch Synthesis

Shipilin, M. (Corresponding author)Extern* ; Degerman, D.Extern* ; Lömker, P.Extern*DESY* ; Goodwin, C. M.Extern* ; Rodrigues, G. L. S. ; Wagstaffe, M.DESY* ; Gladh, J.Extern* ; Wang, H.-Y. ; Stierle, A.XFEL.EU*DESY* ; Schlueter, C.DESY* ; Pettersson, L. G. M.Extern*XFEL.EU* ; Nilsson, A. (Corresponding author)Extern* ; Amann, P.Extern*

2022
ACS Washington, DC

This record in other databases:        

Please use a persistent id in citations: doi:10.1021/acscatal.2c00905  doi:10.3204/PUBDB-2022-03141

Abstract: Carbide formation on iron-based catalysts is an integral and, arguably, the most important part of the Fischer–Tropsch synthesis process, converting CO and H2 into synthetic fuels and numerous valuable chemicals. Here, we report an in situ surface-sensitive study of the effect of pressure, temperature, time, and gas feed composition on the growth dynamics of two distinct iron–carbon phases with the octahedral and trigonal prismatic coordination of carbon sites on an Fe(110) single crystal acting as a model catalyst. Using a combination of state-of-the-art X-ray photoelectron spectroscopy at an unprecedentedly high pressure, high-energy surface X-ray diffraction, mass spectrometry, and theoretical calculations, we reveal the details of iron surface carburization and product formation under semirealistic conditions. We provide a detailed insight into the state of the catalyst’s surface in relation to the reaction.

---

Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)
2. Experimentebetreuung PETRA III (FS-PET-S)
3. Nanolab (FS-NL)

Research Program(s):

1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
3. FS-Proposal: I-20200092 EC (I-20200092-EC) (I-20200092-EC)
4. FS-Proposal: I-20181131 EC (I-20181131-EC) (I-20181131-EC)
5. SWEDEN-DESY - SWEDEN-DESY Collaboration (2020_Join2-SWEDEN-DESY) (2020_Join2-SWEDEN-DESY)
6. CALIPSOplus - Convenient Access to Light Sources Open to Innovation, Science and to the World (730872) (730872)

Experiment(s):

1. PETRA Beamline P22 (PETRA III)
2. PETRA Beamline P21.2 (PETRA III)

Appears in the scientific report 2022

---

Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Essential Science Indicators ; IF >= 10 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

---