Journal Article PUBDB-2021-00542

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Influence of Thermal Activation of Titania on Photoreactivity of Pt/TiO2 in Hydrogen Production

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2020
Springer Science + Business Media B.V Dordrecht [u.a.]

Catalysis letters 151, 748 – 754 () [10.1007/s10562-020-03321-w]
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Abstract: A series of Pt/TiO2 photocatalysts was prepared by impregnation of fresh and thermal-activated titania (commercial Evonik Aeroxide P25 TiO2) with an aqueous solution of H2PtCl6 followed by reduction in an aqueous solution of NaBH4. The thermal activation was performed by annealing in air. The photocatalytic activity of the Pt/TiO2 catalysts was measured for the hydrogen production from a mixture of glycerol under UV radiation. It was found that the activation at 300–600 °C provides an increase in the photoreactivity of resulting Pt/TiO2 photocatalysts in the production of hydrogen while its structural and textural properties do not change. This effect is due to formation of cationic vacancies that limits fast electron–hole recombination.

Classification:

Contributing Institute(s):
  1. Experimentebetreuung PETRA III (FS-PET-S)
Research Program(s):
  1. 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) (POF3-621)
  2. 6G3 - PETRA III (POF3-622) (POF3-622)
Experiment(s):
  1. PETRA Beamline P65 (PETRA III)

Appears in the scientific report 2020
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Medline ; Embargoed OpenAccess ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Springer ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2021-01-20, last modified 2025-07-16


Published on 2020-08-06. Available in OpenAccess from 2021-08-06.:
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