Journal Article PUBDB-2021-00408

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png
Polaritonic Chemistry: Collective Strong Coupling Implies Strong Local Modification of Chemical Properties

 ;  ;  ;

2021
ACS Washington, DC

The journal of physical chemistry letters 12(1), 508 - 516 () [10.1021/acs.jpclett.0c03436]
 GO

This record in other databases:        

Please use a persistent id in citations: doi:  doi:

Abstract: A fundamental question in the field of polaritonic chemistry is whether collective coupling implies local modifications of chemical properties scaling with the ensemble size. Here we demonstrate from first-principles that an impurity present in a collectively coupled chemical ensemble features such locally scaling modifications. In particular, we find the formation of a novel dark state for a nitrogen dimer chain of variable size, whose local chemical properties are altered considerably at the impurity due to its embedding in the collectively coupled environment. Our simulations unify theoretical predictions from quantum optical models (e.g., collective dark states and bright polaritonic branches) with the single molecule quantum chemical perspective, which relies on the (quantized) redistribution of charges leading to a local hybridization of light and matter. Moreover, our findings suggest that recently developed ab initio methods for strong light-matter coupling are suitable to access these local polaritonic effects and provide a detailed understanding of photon-modified chemistry.

Classification:

Contributing Institute(s):
  1. Forschungsgruppe für strukturelle Dynamik (MPSD)
  2. MPSD (CFEL-MPT)
Research Program(s):
  1. 899 - ohne Topic (POF4-899) (POF4-899)
Experiment(s):
  1. No specific instrument

Appears in the scientific report 2021
Database coverage:
Medline ; OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Essential Science Indicators ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
Click to display QR Code for this record

The record appears in these collections:
Private Collections > >CFEL > >MPSD > CFEL-MPT
Document types > Articles > Journal Article
Private Collections > >MPG > MPSD
Public records
Publications database
OpenAccess

 Record created 2021-01-15, last modified 2025-07-24


OpenAccess:
Download fulltext PDF Download fulltext PDF (PDFA)
Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)