Journal Article PUBDB-2020-05121

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Swelling of Steel Film by Hydrogen Absorption at Cathodic Potential in Electrolyte

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2020
Wiley-VCH Weinheim

Physica status solidi / B 257(6), 2070027 - () [10.1002/pssb.202070027]
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Abstract: A 4‐nm‐thick alloy film with a metal composition close to AISI 304 stainless steel, deposited on a multilayer, was investigated by Jörg Zegenhagen and co‐workers (article number 2000055) as a model of the stainless‐steel surface region crucial for pitting corrosion. Using the X‐ray standing wave method, the oxidation states of iron, chrome and nickel as well as film composition and changes after electrolyte exposure are resolved depth‐selectively. Hydrogen loading by exposure to 0.1 M KCl at cathodic potential leads to swelling of the film by 11%, thus decreasing the resistance to pitting corrosion and finally leading to embrittlement.

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Contributing Institute(s):
  1. DOOR-User (DOOR ; HAS-User)
Research Program(s):
  1. 6G3 - PETRA III (POF3-622) (POF3-622)
Experiment(s):
  1. PETRA Beamline P64 (PETRA III)

Appears in the scientific report 2020
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 Record created 2020-12-18, last modified 2025-07-29


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