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Journal Article PUBDB-2019-02655

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Inner-shell X-ray absorption spectra of the cationic series $\mathrm{NH_y^+ ( y = 0–3)}$

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2019
RSC Publ. Cambridge

Physical chemistry, chemical physics 21(30), 16505-16514 () [10.1039/C9CP02864A]
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Abstract: Ion yields following X-ray absorption of the cationic series $\mathrm{NH_y^+ ( y = 0–3)}$ were measured to identify the characteristic absorption resonances in the energy range of the atomic nitrogen K-edge. Significant changes in the position of the absorption resonances were observed depending on the number of hydrogen atoms bound to the central nitrogen atom. Configuration interaction (CI) calculations were performed to obtain line assignments in the frame of molecular group theory. To validate the calculations, our assignment for the atomic cation N$^+$, measured as a reference, was compared with published theoretical and experimental data.

Classification:

Contributing Institute(s):
  1. Strukturdynamik Chemischer Systeme (FS-SCS)
  2. FS-PETRA (FS-PETRA)
  3. FS-CFEL-3 (CFEL-DESYT)
  4. FS-FLASH (CFEL-UDSS)
  5. DOOR-User (DOOR ; HAS-User)
  6. CFEL-Theory (FS-CFEL-3)
Research Program(s):
  1. 6211 - Extreme States of Matter: From Cold Ions to Hot Plasmas (POF3-621) (POF3-621)
  2. 6G3 - PETRA III (POF3-622) (POF3-622)
  3. FS-Proposal: I-20160124 (I-20160124) (I-20160124)
Experiment(s):
  1. PETRA Beamline P04 (PETRA III)

Appears in the scientific report 2019
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Medline ; Creative Commons Attribution CC BY 4.0 ; OpenAccess ; Allianz-Lizenz / DFG ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; National-Konsortium ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection
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Private Collections > >DESY > >FS > FS-PETRA
Private Collections > >DESY > >FS > FS-SCS
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 Record created 2019-07-04, last modified 2025-07-16


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