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| Journal Article | PUBDB-2019-00732 |
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2019
RSC
Cambridge
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Please use a persistent id in citations: doi:10.1039/C8SC05471A doi:10.3204/PUBDB-2019-00732
Abstract: Pentaphosphaferrocene [Cp*Fe(η$^5$-P$_5$)] in combination with Cu(I) halides is capable of a template-directed synthesis of fullerene-like spheres. Herein, we present the use of a triple decker complex as template that leads to the formation of unprecedented ‘nano-bowls’. These spherical domes resemble the truncated fullerenes $I_{h}-C_{80}$ and represent a novel spherical arrangement in the chemistry of spherical molecules.
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