| Home > Publications database > $\mathrm{KNH_{2}–KH}$: a metal amide–hydride solid solution |
| Journal Article | PUBDB-2016-06032 |
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2016
Soc.
Cambridge
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Please use a persistent id in citations: doi:10.1039/C6CC05777B doi:10.3204/PUBDB-2016-06032
Abstract: We report for the first time the formation of a metal amide–hydridesolid solution. The dissolution of KH into KNH$_2$ leads to an anionicsubstitution, which decreases the interaction among NH$_2$-ions.The rotational properties of the high temperature polymorphs of KNH$_2$ are thereby retained down to room temperature.
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