Journal Article

PUBDB-2015-04796

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Compound semiconductor alloys: From atomic-scale structure to bandgap bowing

Schnohr, C. (Corresponding author)>Extern*

2015
AIP New York, NY

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Please use a persistent id in citations: doi:10.1063/1.4930002

Abstract: Compound semiconductor alloys such as In$_{x}$Ga$_{1-x}$As, GaAsxP$_{1-x}$, or CuIn$_{x}$Ga$_{1-x}$Se$_{2}$ are increasingly employed in numerous electronic, optoelectronic, and photonic devices due to the possibility of tuning their properties over a wide parameter range simply by adjusting the alloy composition. Interestingly, the material properties are also determined by the atomic-scale structure of the alloys on the subnanometer scale. These local atomic arrangements exhibit a striking deviation from the average crystallographic structure featuring different element-specific bond lengths, pronounced bond angle relaxation and severe atomic displacements. The latter, in particular, have a strong influence on the band gap energy and give rise to a significant contribution to the experimentally observed band gap bowing. This article therefore reviews experimental and theoretical studies of the atomic-scale structure of III-V and II-VI zincblende alloys and I-III-VI$_{2}$ chalcopyrite alloys and explains the characteristic findings in terms of bond length and bond angle relaxation. Different approaches to describe and predict the band gap bowing are presented and the correlation with local structural parameters is discussed in detail. The article further highlights both similarities and differences between the cubic zincblende alloys and the more complex chalcopyrite alloys and demonstrates that similar effects can also be expected for other tetrahedrally coordinated semiconductors of the adamantine structural family.

Note: (c) AIP Publishing LLC

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Contributing Institute(s):

1. DOOR-User (DOOR)

Research Program(s):

1. 899 - ohne Topic (POF3-899) (POF3-899)
2. FS-Proposal: I-20110135 (I-20110135) (I-20110135)
3. FS-Proposal: I-20100027 (I-20100027) (I-20100027)

Experiment(s):

1. DORIS Beamline C (DORIS III)

Appears in the scientific report 2015

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Database coverage:
; ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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