Journal Article PHPPUBDB-12135

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Biaxially Oriented CdSe Nanorods

 ;  ;  ;  ;  ;  ; DESY

2009
ACS Publ. Washington, DC

Langmuir 25, 10970-10974 () [10.1021/la9011795]
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Abstract: The shape, structure, and orientation of rubbing-aligned cadmium selenide (CdSe) nanorods on polymer coated glass substrates have been studied using transmission electron microscopy (TEM) and grazing incidence X-ray scattering combined with computer simulations. The nanorods are found to be of wurtzite structure and highly monodisperse, and have an essentially ellipsoidal shape with short axes of approximately 8 nm and long axis of approximately 22 nm. The nanorods exhibit preferred biaxial orientation with the hexagonal a-c-plane parallel to the sample surface and the c-axis oriented along the rubbing direction of the sample. Some tendency of smectic-A ordering is observed. A quantitative model incorporating atomic structure, rod shape, and preferred orientation was developed for numerically simulating the diffraction peak positions, widths, and intensities, giving good correlation with the experimental observations.

Classification:

Note: © American Chemical Society

Contributing Institute(s):
  1. Experiments with synchrotron radiation (HASYLAB(-2012))
Research Program(s):
  1. DORIS Beamline BW2 (POF1-550) (POF1-550)
  2. FS-Proposal: II-20060221 EC (II-20060221-EC) (II-20060221-EC)
Experiment(s):
  1. DORIS Beamline BW2 (DORIS III)

Appears in the scientific report 2009
Notes: (c) American Chemical Society. No copyright permission for full text.
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 Record created 2012-09-19, last modified 2025-07-31


Published on 2009-07-02. Available in OpenAccess from 2010-07-02.:
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