Journal Article

PHPPUBDB-16658

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Rotational-state-specific guiding of large molecules

Putzke, S. ; Filsinger, F.>Extern* ; Haak, H. ; Küpper, J. (Corresponding Author)CFEL*DESY* ; Meijer, G. ; DESY

2011
RSC Publ. Cambridge

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Please use a persistent id in citations: doi:10.1039/c1cp20721k

Abstract: A beam of polar molecules can be focused and transported through an ac electric quadrupole guide. At a given ac frequency, the transmission of the guide depends on the mass-to-dipole-moment (m/μ) ratio of the molecular quantum state. Here we present a detailed characterization of the m/μ selector, using a pulsed beam of benzonitrile (C(6)H(5)CN) molecules in combination with rotational quantum state resolved detection. The arrival time distribution as well as the transverse velocity distribution of the molecules exiting the selector are measured as a function of ac frequency. The μ/Δμ resolution of the selector can be controlled by the applied ac waveforms and a value of up to 20 can be obtained with the present setup. This is sufficient to exclusively transmit benzonitrile molecules in quantum states with the same m/μ value as the absolute ground state. The operation characteristics of the m/μ selector are in quantitative agreement with the outcome of trajectory simulations.

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Contributing Institute(s):

1. CFEL-Coherent X-Ray Imaging (FS-CFEL-1)
2. CFEL-CMI (FS-CFEL-CMI)

Research Program(s):

1. 54x - Programm Forschung mit Photonen, Neutronen, Ionen - Topic unbekannt (POF2-54x) (POF2-54x)

Experiment(s):

1. No specific instrument

Appears in the scientific report 2011
Notes: (c) Royal Society of Chemistry

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Database coverage:
; JCR ; No Author Disambiguation ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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