Stabilisation of a Highly Reactive Bis(mu-oxo)dicopper(III) Species at Room Temperature by Electronic and Steric Constraint of an Unconventional Nitrogen Donor Ligand.

Herres-Pawlis, S.; Wellenreuther, G.; Eich, A.; Binder, S.; Meyer-Klaucke, W.; Rübhausen, M.; Henkel, G.; Schulz, B.; Haase, R.

doi:10.1002/chem.200901092

Journal Article

Stabilisation of a Highly Reactive Bis(mu-oxo)dicopper(III) Species at Room Temperature by Electronic and Steric Constraint of an Unconventional Nitrogen Donor Ligand.

Herres-Pawlis, S. (Corresponding author)Extern* ; Binder, S. ; Eich, A. ; Haase, R. ; Schulz, B. ; Wellenreuther, G. ; Henkel, G. (Corresponding author)Extern* ; Rübhausen, M. (Corresponding author)CFEL*Extern* ; Meyer-Klaucke, W. (Corresponding author)DESY* ; DESY

2009
Wiley-VCH Weinheim

Chemistry 15, 8678-8682 (2009) [10.1002/chem.200901092]

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Please use a persistent id in citations: doi:10.1002/chem.200901092

Abstract: The bis(guanidine) ligand N$^1$,N$^3$‐bis[bis(2,2,6,6‐tetramethylpiperidin‐1‐yl)methylen]propan‐1,3‐diamine stabilizes the first bis(μ‐oxo)dicopper(III) complex (see figure) at room temperature. This complex is characterized in the ground state and in the optical excited state by a combination of EXAFS and resonance Raman spectroscopy

Keyword(s): Copper: chemistry (MeSH) ; Ligands (MeSH) ; Molecular Structure (MeSH) ; Nitrogen: chemistry (MeSH) ; Organometallic Compounds: chemistry (MeSH) ; Oxygen: chemistry (MeSH) ; Spectrum Analysis, Raman (MeSH) ; Ligands ; Organometallic Compounds ; Copper ; Nitrogen ; Oxygen