Journal Article PUBDB-2026-00709

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Engineered Self‐Assembly of Plasmonic Gold Nanoparticles Into Two‐Dimensional and Three‐Dimensional Arrays Within the Pores of Porous Silicon Membranes

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2026
Wiley Weinheim

ChemNanoMat 12(2), e202500594 () [10.1002/cnma.202500594]
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Abstract: We report a facile centrifugation-based method for assembling polystyrene (PSSH)-functionalized gold nanoparticles (Au NPs)onto porous silicon (pSi) substrates in two distinct configurations: two- and three-dimensional (2D and 3D) assemblies. The 2Dassemblies are densely packed monolayer coatings of the exposed Si-surfaces including the inner pore walls, whereas the 3Dstructures result from Au NPs clustering inside the pores. Remarkably, this shift from 2D to 3D architectures was achievedby minor modification of the PSSH coating thickness. Scanning electron microscopy (SEM) characterization confirmed the homo-geneity and high packing density of these assemblies extending over several thousand square micrometers. This approach offers astraightforward and versatile route for the fabrication of well-ordered pSi–Au NP hybrid nanostructures with potential applica-tions in catalysis, surface-enhanced spectroscopy and optical metamaterials.

Classification:

Contributing Institute(s):
  1. CIMMS-RA Center for integr. Multiscale M (CIMMS)
Research Program(s):
  1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
  2. DFG project G:(GEPRIS)533771286 - EXC 3120: BlueMat: Wassergesteuerte Materialien (533771286) (533771286)
Experiment(s):
  1. No specific instrument

Appears in the scientific report 2026
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Medline ; Creative Commons Attribution CC BY 4.0 ; OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Essential Science Indicators ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2026-02-11, last modified 2026-02-13


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