Journal Article

PUBDB-2025-03957

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Experimental signatures of interstitial electron density in transparent dense sodium

Storm, C. (Corresponding author)Extern* ; Racioppi, S. ; Duff, M.Extern* ; McHardy, J.Extern* ; Zurek, E. ; McMahon, M.Extern*

2025
Springer Nature London

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Please use a persistent id in citations: doi:10.1038/s43246-025-00925-w  doi:10.3204/PUBDB-2025-03957

Abstract: The transparent hP4 phase of dense sodium (Na), stable above 200 GPa, has been computed to be an electride in which valence electrons are localised on interstitial lattice sites within the structure. However, there is no experimental evidence for this interstitial electron localisation in Na, or indeed in other high-density electride phases. Using static compression and single-crystal X-ray diffraction techniques, we have grown and studied a single-crystal sample of Na in the hP4 phase at 223 GPa. Using atomic form factors for hP4-Na derived from quantum crystallography techniques, we present experimental results to support the electride nature of this phase.

Note: For the purpose of open access, the author has applied a Creative Commons Attribution (CC BY) license to any Author Accepted Manuscript version arising from this submission.

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Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)

Research Program(s):

1. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
2. FS-Proposal: I-20220638 (I-20220638) (I-20220638)

Experiment(s):

1. PETRA Beamline P02.2 (PETRA III)

Appears in the scientific report 2025

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