Journal Article PUBDB-2023-07958

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Modulating Thermal Properties of Polymers through Crystal Engineering

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2023
Wiley-VCH Weinheim

Angewandte Chemie 62(19), e202212688 () [10.1002/anie.202212688]
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Abstract: Crystal engineering has exclusively focused on the development of advanced materials based on small organic molecules. We now demonstrate how the cocrystallization of a polymer yields a material with significantly enhanced thermal stability but equivalent mechanical flexibility. Isomorphous replacement of one of the cocrystal components enables the formation of solid solutions with melting points that can be readily fine-tuned over a usefully wide temperature range. The results of this study credibly extend the scope of crystal engineering and cocrystallization from small molecules to polymers.

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Contributing Institute(s):
  1. DOOR-User (DOOR ; HAS-User)
Research Program(s):
  1. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
Experiment(s):
  1. PETRA Beamline P02.1 (PETRA III)

Appears in the scientific report 2023
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 Record created 2023-12-19, last modified 2025-07-24


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