Journal Article

PUBDB-2023-06260

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Room-Temperature Triethylamine Sensor Based on Reduced Graphene Oxide/CeO$_2$ Nanocomposites

Zito, C. A.Extern* ; Perfecto, T. M. ; Volanti, D. P. (Corresponding author)

2023
ACS Publications Washington, DC

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Please use a persistent id in citations: doi:10.1021/acsanm.3c01734  doi:10.3204/PUBDB-2023-06260

Abstract: Triethylamine (TEA) detection has been widely performed by using chemoresistive sensors. Nevertheless, chemoresistive sensors still exhibit limitations to be addressed in terms of power consumption and humidity interference, and developing efficient TEA sensors operated at low temperatures and humid conditions remains a challenge. Here, we present the effect of reduced graphene oxide (RGO) on the TEA-sensing performance of CeO$_2$ nanospheres at room temperature and a relative humidity (RH) range of 34–70%. We show that CeO$_2$ is a suitable sensing material for TEA detection at room temperature and humidity conditions; however, the modification with RGO greatly improves the TEA-sensing performance. The RGO/CeO$_2$ nanocomposite has higher sensitivity and selectivity to TEA than the bare CeO$_2$-based sensor, in addition to the low theoretical detection limit of 1 ppm at 70% RH. Moreover, we elucidate that humidity plays a positive role in the detection of TEA. Our findings elucidate that RGO positively affects the sensing performance of CeO$_2$ nanospheres, which can be attributed to the improvements in the baseline electrical resistance and enhancement of the active sites for TEA adsorption due to the RGO modification. This work provides a promising strategy for developing sensitive TEA sensors with practical applications.

Note: Copyright © 2023 American Chemical Society Non-open access journal

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Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)

Research Program(s):

1. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)

Experiment(s):

1. PETRA Beamline P07 (PETRA III)

Appears in the scientific report 2023

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Database coverage:
; ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Essential Science Indicators ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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