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Journal Article | PUBDB-2023-03468 |
; ; ; ; ;
2024
American Chemical Society
Washington, DC
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Please use a persistent id in citations: doi:10.1021/acs.jpca.3c07958 doi:10.3204/PUBDB-2023-03468
Abstract: Water dimer $\mathrm{(H_2O)_2}$ -- a vital component of the earth's atmosphere -- is an important prototypical hydrogen-bonded system providing insight into fundamental chemical and biochemical processes, \eg, proton transfer and ionic supramolecular dynamics occurring in astro- and atmospheric chemistry. We report the simultaneous detection of all generated ion products of $\mathrm{(H_2O)_2^+}$-fragmentation induced by strong-field ionization using a purified molecular beam of water dimers and multi-mass imaging. Detailed information about reaction energetics and absolute relative ion yields of the ion-radical pathways of $\mathrm{(H_2O)_2^+}$ are presented.
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Reaction Pathways of Water Dimer Following Single Ionization
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