Journal Article PUBDB-2023-03468

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Reaction Pathways of Water Dimer Following Single Ionization

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2024
American Chemical Society Washington, DC

The journal of physical chemistry / A 128(9), 1593-1599 () [10.1021/acs.jpca.3c07958]
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Abstract: Water dimer $\mathrm{(H_2O)_2}$ -- a vital component of the earth's atmosphere -- is an important prototypical hydrogen-bonded system providing insight into fundamental chemical and biochemical processes, \eg, proton transfer and ionic supramolecular dynamics occurring in astro- and atmospheric chemistry. We report the simultaneous detection of all generated ion products of $\mathrm{(H_2O)_2^+}$-fragmentation induced by strong-field ionization using a purified molecular beam of water dimers and multi-mass imaging. Detailed information about reaction energetics and absolute relative ion yields of the ion-radical pathways of $\mathrm{(H_2O)_2^+}$ are presented.

Classification:

Contributing Institute(s):
  1. CFEL-CMI (FS-CFEL-CMI)
Research Program(s):
  1. 631 - Matter – Dynamics, Mechanisms and Control (POF4-631) (POF4-631)
  2. HIRS-0018 - Helmholtz-Lund International School - Intelligent instrumentation for exploring matter at different time and length scales (HELIOS) (2020_HIRS-0018) (2020_HIRS-0018)
  3. DFG project 390715994 - EXC 2056: CUI: Advanced Imaging of Matter (390715994) (390715994)
  4. DFG project 194651731 - EXC 1074: Hamburger Zentrum für ultraschnelle Beobachtung (CUI): Struktur, Dynamik und Kontrolle von Materie auf atomarer Skala (194651731) (194651731)
Experiment(s):
  1. Experiments at CFEL

Appears in the scientific report 2024
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Reaction Pathways of Water Dimer Following Single Ionization
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 Record created 2023-05-25, last modified 2025-07-18


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