Journal Article PUBDB-2022-06318

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Unravelling the synthesis of a rare-earth cluster-based metal–organic framework with spn topology

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2022
Soc. Cambridge

Chemical communications 58(78), 10925 - 10928 () [10.1039/D2CC03575H]
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Abstract: Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality material. Y-CU-45 shows high crystallinity and surface area, shining light on the potential for rare-earth cluster-based MOFs with open metal sites.

Classification:

Contributing Institute(s):
  1. Strukturdynamik Chemischer Systeme (FS-SCS)
Research Program(s):
  1. 633 - Life Sciences – Building Blocks of Life: Structure and Function (POF4-633) (POF4-633)
  2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
  3. SFB 1073 C02 - In-situ hochauflösende Untersuchung des aktiven Zustands bei der (photo-) elektrochemischen Wasserspaltung (C02) (240172646) (240172646)
  4. SFB 1073 B06 - Echtzeituntersuchungen der optischen Anregung in oligonuklearen Metallkomplexen mit schaltbaren Spin- und Ladungszuständen (B06) (240171831) (240171831)
Experiment(s):
  1. PETRA Beamline P11 (PETRA III)

Database coverage:
Medline ; Embargoed OpenAccess ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 5 ; Index Chemicus ; JCR ; National-Konsortium ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2022-11-02, last modified 2025-07-15


Published on 2022-08-25. Available in OpenAccess from 2023-08-25.:
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