Journal Article

PUBDB-2022-05392

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Formation of new crystalline qtz-[Zn(mIm)$_2$] polymorph from amorphous ZIF-8

Thorne, M. F.Extern* ; Castillo-Blas, C.Extern* ; McHugh, L. N. ; Bumstead, A. M. ; Robertson, G. ; Sapnik, A. F. ; Coates, C. S. ; Sayed, F. N. ; Grey, C. P. ; Keen, D. A.Extern*XFEL.EU* ; Etter, M.DESY* ; da Silva, I. ; Užarević, K.Extern* ; Bennett, T. D. (Corresponding author)

2022
Soc. Cambridge

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Please use a persistent id in citations: doi:10.1039/D2CC04241J  doi:10.3204/PUBDB-2022-05392

Abstract: The structure of a new ZIF-8 polymorph with quartz topology (qtz) is reported. This qtz-[Zn(mIm)$_2$] phase was obtained by mechanically amorphising crystalline ZIF-8, before heating the resultant amorphous phase to between 282 and 316 °C. The high-temperature phase structure was obtained from powder X-ray diffraction, and its thermal behaviour, CO$_2$ gas sorption properties and dye adsorption ability were investigated.

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Contributing Institute(s):

1. DOOR-User (DOOR ; HAS-User)
2. PETRA-D (FS-PETRA-D)

Research Program(s):

1. 631 - Matter – Dynamics, Mechanisms and Control (POF4-631) (POF4-631)
2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)

Experiment(s):

1. PETRA Beamline P02.1 (PETRA III)

Appears in the scientific report 2022

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Database coverage:
; ; ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 5 ; Index Chemicus ; JCR ; National-Konsortium ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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