Journal Article

PUBDB-2016-04585

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Superspace description of trimethyltin hydroxide at T = 100 K

Dey, S.Extern* ; Schönleber, A. (Corresponding author)Extern* ; Mondal, S.Extern* ; van Smaalen, S.Extern*

2016
De Gruyter Berlin

This record in other databases:    

Please use a persistent id in citations: doi:10.1515/zkri-2016-1952  doi:10.3204/PUBDB-2016-04585

Abstract: At low temperatures the metalorganic compound trimethyltin hydroxide, (CH$_3$)$_3$SnOH, possesses a commensurately modulated crystal structure, the modulation wave vector can be described as $q = \frac{1}{2} c*$. The crystal structure is studied by analysing single-crystal X-ray diffraction data within the (3+1)-dimensional superspace approach and superspace group P21212(00γ)00s. The corresponding twofold superstructure has space group symmetry P2$_1$2$_1$2$_1$. The structure is characterised by polymeric chains running along c-axis, generated by Sn–O–Sn bridges between neighbouring Sn atoms and packed in a distorted hexagonal pattern and linked via C–H···O interstrand hydrogen bonds along the (orthorhombic) directions [110] and [11̅0], but not along [100].

Note: (c) de Gruyter

---

Contributing Institute(s):

1. DOOR-User (DOOR)

Research Program(s):

1. 899 - ohne Topic (POF3-899) (POF3-899)

Experiment(s):

1. DORIS Beamline F1 (DORIS III)

Appears in the scientific report 2016

---

Database coverage:
; ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

---