| Home > Publications database > Germanene: a Novel Two-Dimensional Germanium Allotrope Akin to Graphene and Silicene |
| Journal Article | PUBDB-2016-03151 |
; ; ; ;
2014
Dt. Physikalische Ges.
[Bad Honnef]
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Please use a persistent id in citations: doi:10.1088/1367-2630/16/9/095002
Abstract: We have grown an atom-thin, ordered, two-dimensional multi-phase film in situ through germanium molecular beam epitaxy using a gold (111) surface as a substrate. Its growth is similar to the formation of silicene layers on silver (111) templates. One of the phases, forming large domains, as observed in scanning tunneling microscopy, shows a clear, nearly flat, honeycomb structure. Thanks to thorough synchrotron radiation core-level spectroscopy measurements and advanced density functional theory calculations we can identify it as a $\sqrt{3}$ × $\sqrt{3}$ $R$(30$^\circ$) germanene layer in conjunction with a $\sqrt{ 7 } \times \sqrt{ 7 } $R$(19.1$^{\circ}$ Au(111) supercell, presenting compelling evidence of the synthesis of the germaniumbased cousin of graphene on gold.
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