Journal Article PUBDB-2015-05292

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Phase Equilibria in the $\mathrm{B–BN–B_{2}O_{3}}$ System at 5 GPa

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2013
Soc. Washington, DC

The journal of physical chemistry <Washington, DC> / C 117(36), 18642 - 18647 () [10.1021/jp407407t]
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Abstract: Phase equilibria in the B–BN–B$_{2}$O$_{3}$ ternary system at pressures up to 5 GPa have been studied by in situ probing with synchrotron X-ray powder diffraction, microscopic and X-ray diffraction characterization of recovered samples, and thermodynamic analysis. The phase diagram of the system has been constructed by combining the previously reported data for binary subsystems and a conventional phenomenological model describing ternary interactions. The interaction parameter of the model of the ternary liquid phase has been determined by adjustment of experimental melting points to the calculated monovariant eutectic curve. The phase diagram is characterized by two ternary eutectics, one ternary transition-type equilibrium, and the maximum in the monovariant eutectic curve.

Classification:

Note: (c) American Chemical Society

Contributing Institute(s):
  1. DOOR-User (DOOR)
Research Program(s):
  1. 6G3 - PETRA III (POF3-622) (POF3-622)
  2. FS-Proposal: I-20080149 EC (I-20080149-EC) (I-20080149-EC)
  3. FS-Proposal: I-20120445 EC (I-20120445-EC) (I-20120445-EC)
Experiment(s):
  1. DORIS Beamline F2.1 (DORIS III)

Appears in the scientific report 2013
Database coverage:
Medline ; ClosedAccess ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2015-12-04, last modified 2021-11-10


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