Journal Article DESY-2013-00948

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Intrinsic and impurity luminescence of rare earth ions doped KY$F_4$ nanophosphors

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2013
Elsevier Science Amsterdam [u.a.]

Radiation measurements 56, 393 - 396 () [10.1016/j.radmeas.2013.01.070]
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Abstract: The KYF4 nanopowders, non-doped and doped with Ce3+ or Tb3+, having well-crystallized, unaggregated, monodisperse (±15%) nanoparticles with the cubic (the size in the range from ∼15 to ∼30 nm) or hexagonal (from ∼30 to ∼50 nm) crystal structure have been successfully synthesized by microwave-hydrothermal treatment of as-precipitated gels. In KYF4 hexagonal nanopowders an intense STE-type luminescence at ∼4.4 eV was observed which is not quenched at room temperature. In contrast to single crystals or cubic nanopowders, in KYF4 hexagonal nanopowders doped with Ce3+ or Tb3+, a rather efficient energy transfer is observed from the host to Ce3+ or Tb3+ ions, respectively, because of overlapping the emission spectrum of STE-type luminescence and the spectrum of efficient absorption on 4f-5d transitions in Ce3+ or Tb3+.

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Note: © Elsevier Ltd.

Contributing Institute(s):
  1. FS-Experimentebetreuung DORIS (FS-DO)
  2. DOOR-User (DOOR)
Research Program(s):
  1. DORIS Beamline I (POF2-54G13) (POF2-54G13)
  2. FS-Proposal: I-20110873 EC (I-20110873-EC) (I-20110873-EC)
  3. CALIPSO - Coordinated Access to Lightsources to Promote Standards and Optimization (312284) (312284)
Experiment(s):
  1. DORIS Beamline I (DORIS III)

Appears in the scientific report 2013
Database coverage:
Medline ; Embargoed OpenAccess ; JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection ; Zoological Record
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 Record created 2013-10-21, last modified 2025-07-30


Published on 2013-01-30. Available in OpenAccess from 2014-01-30.:
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