Journal Article

PUBDB-2025-05212

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Crystal structure of tris[hexakis(imidazole)cobalt(II)] bis(benzene-1,3,5-tricarboxylate)

Velazquez-Garcia, J. d. J. (Corresponding author) ; Bintas, C. ; Khademhir, F. ; Knjo, B. ; Ekineken, A. ; Hain, F. ; Techert, S. (Corresponding author)XFEL.EU*DESY*

2025
International Union of Crystallography Chester

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Please use a persistent id in citations: doi:10.1107/S2056989025010060

Abstract: The title compound, [CoII(C3H4N2)6]3(C9H3O6)2 (1), was synthesized from cobalt chloride(II), benzene-1,3,5-tricarboxylic acid (H3btc) and imidazole (Im) in an ethanol/DMF mixture via slow evaporation at room temperature. This compound consists of three hexakis(imidazole)cobalt(II) cations and two trimesate anions. Examination of the crystal packing shows the formation of one-dimensional stacksc axis. The packing interactions are primarily driven by N—H...O hydrogen bonding between anions and cations.

Note: ISSN 2056-9890 not unique: **2 hits**.

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Contributing Institute(s):

1. Strukturdynamik Chemischer Systeme (FS-SCS)

Research Program(s):

1. 633 - Life Sciences – Building Blocks of Life: Structure and Function (POF4-633) (POF4-633)
2. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)
3. SFB 1073 C02 - In-situ hochauflösende Untersuchung des aktiven Zustands bei der (photo-) elektrochemischen Wasserspaltung (C02) (240172646) (240172646)

Experiment(s):

1. PETRA Beamline P11 (PETRA III)
2. PETRA Beamline P24 (PETRA III)
3. Measurement at external facility

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Database coverage:
; ; ; Article Processing Charges ; Clarivate Analytics Master Journal List ; DOAJ Seal ; Ebsco Academic Search ; Emerging Sources Citation Index ; Fees ; IF < 5 ; JCR ; SCOPUS ; Web of Science Core Collection

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