Documents in process

Our planet is flooded with plastics and the need for sustainable recycling strategies of polymers has become increasingly urgent. Enzyme-based hydrolysis of post-consumer plastic is an emerging strategy for closed-loop recycling of polyethylene terephthalate (PET). [...]

The efficient recovery of noble metal nanocrystals used in heterogeneous organic transformations has remained a significant challenge, hindering their use in industry. Herein, highlycatalytic Pd nanoparticles (NPs) were first prepared having a yield of >98% by a novel hydrothermal method using PVP as the reducing cum stabilizing agent that exhibited excellent turnover frequencies of ∼38,000 h−1 for Suzuki−Miyaura cross-coupling and ∼1200 h−1 for catalytic reduction of nitroarene compounds in a benign aqueous reaction medium. [...]

The TSC complex is a critical negative regulator of the small GTPase Rheb and mTORC1 in cellular stress signaling. The TSC2 subunit contains a catalytic GTPase activating protein domain and interacts with multiple regulators, while the precise function of TSC1 is unknown. [...]

Many bacteria export intracellular calcium using active transporters homologous to the sarco/endoplasmic reticulum Ca2+-ATPase (SERCA). Here we present three crystal structures of Ca2+-ATPase 1 from Listeria monocytogenes (LMCA1). [...]

e have deduced the structure of the bromobenzene-$I_2$ heterodimer and the bromobenzene homodimer inside helium droplets using a combination of laser-induced alignment, Coulomb explosion imaging, and three-dimensional ion imaging. The complexes were fixed in a variety of orientations in the laboratory frame, then in each case multiply ionized by an intense laser pulse [...]

Industrial Cu/ZnO/Al2O3 or novel rate catalysts, prepared with a photochemical deposition method, were studied under functional CH3OH synthesis conditions at the set temperature (T) range of 240–350 °C, 20 bar pressure, and stoichiometric carbon dioxide/hydrogen composition. Analytical scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray adsorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) methods were systematically utilized to investigate the interfaces, measured local geometry, and chemical state electronics around the structured active sites of commercially available Cu/ZnO/Al2O3 material or synthesized Cu/ZnO. [...]

The fast and contact-free detection of biomagnetic vital signs can benefit clinical diagnostics in medical care, emergency services, and scientific studies, hugely. A highly sensitive magnetoelectric sensor for the detection of biomagnetic signals combined with the piezotronic effect is a promising path to increase the signal detection limit. [...]

Self‐assembly of iron oxide nanoparticles (IONPs) into 1D chains is appealing, because of their biocompatibility and higher mobility compared to 2D/3D assemblies while traversing the circulatory passages and blood vessels for in vivo biomedical applications. In this work, parameters such as size, concentration, composition, and magnetic field, responsible for chain formation of IONPs in a dispersion as opposed to spatially confining substrates, are examined. [...]

Additive manufacturing (AM) of superalloys has been attracting increasinginterest. While most studies focus on the processability and mechanical propertiesof the finished product, it is also necessary to understand the phasetransformations during the consecutive melting processes. [...]

Additive manufacturing (AM) processes such as electron beam melting (EBM) are characterized by unprecedented design freedom. Topology optimization and design of the microstructure of metallic materials are enabled by rapid progress in this field. [...]