Journal Article PUBDB-2017-08060

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The structure of molten $\mathrm{ZnCl_2}$

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1998
Elsevier Science Amsterdam [u.a.]

Journal of non-crystalline solids 224(3), 205 - 215 () [10.1016/S0022-3093(97)00480-8]
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Abstract: High energy photon diffraction measurements on molten ZnCl2 have been carried out in the temperature range 623–853 K. The momentum transfer range covered is 0.15 Å−1<Q<21.6 Å−1. The sample is investigated in transmission geometry. The data are in good agreement with neutron diffraction measurements. A discrepancy at smaller Q values is to be noted, however, with earlier studies using conventional Mo–Kα X-rays in reflection geometry. By combining neutron and high energy photon results, the partial distribution functions can be separated to some extent. Almost no change of the first Zn–Cl distance is observed with increasing temperature, whereas the distribution of the first shell Cl–Cl distances increases in width and the first shell Zn–Zn distance decreases.

Classification:

Note: F-Bereich; HASYLAB

Contributing Institute(s):
  1. DESY Retrocat (DESY(-2012))
Research Program(s):
  1. 899 - ohne Topic (POF3-899) (POF3-899)
Experiment(s):
  1. No specific instrument

Database coverage:
Medline ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2017-07-20, last modified 2025-08-04


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